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论文类型：期刊论文

发表时间：2020-05-28

发表刊物：NANOSCALE

收录刊物：PubMed、SCIE

卷号：12

期号：20

页面范围：10933-10938

ISSN号：2040-3364

摘要：Compared with the traditional Haber-Bosch process, electrochemical ammonia synthesis has attracted much attention owing to its low energy consumption, low pollution potential, and sustainability. However, owing to the influence of high overpotential and low selectivity, the nitrogen reduction reaction (NRR) process was of limited applicability in industry. Here, we report a high-performance Ru@Ti3C2 MXene catalyst for an ambient electrocatalytic NRR. In a 0.1 M KOH electrolyte, the NH3 yield of the Ru@MXene catalyst reached 2.3 mu mol h(-1) cm(-2), furthermore, at -0.4 V (vs. RHE) the Faraday efficiency was 13.13%.