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论文类型：期刊论文

发表时间：2021-01-10

发表刊物：SUSTAINABLE ENERGY & FUELS

卷号：4

期号：10

页面范围：5061-5071

ISSN号：2398-4902

摘要：The Haber-Bosch process is one of the most widely utilized approaches for the synthesis of ammonia, and has many disadvantages, such as the high energy consumption and generation of large amounts of greenhouse gases. Therefore, the electrochemical nitrogen reduction reaction (NRR) has received significant attention, as it is more sustainable and environmentally friendly. In this study, we report a CuAg/Ti(3)C(2)MXene catalyst for the electrocatalytic NRR. This MXene-based composite material exhibits remarkable performance for electrochemical synthesis of ammonia under ambient conditions. When measured in a 0.1 M KOH solution at an applied potential of -0.5 Vvs.reversible hydrogen electrode (RHE), the catalyst achieved an ammonia production rate and faradaic efficiency of 4.12 mu mol cm(-2)h(-1)and 9.77%, respectively. These values indicate excellent stability and selectivity compared with the previously reported 2D NRR electrocatalysts. Moreover, the results of density functional theory calculations illustrate that with preferable adsorption of N-2, desorption of NH3, and suppression of the HER, CuAg/Ti(3)C(2)is a promising catalyst for the NRR. The excellent electrical conductivity and fast electron transport in the CuAg/Ti(3)C(2)catalyst are favorable for the evaluated electrocatalytic reaction. Both experimental results and DFT calculations reveal that CuAg plays a crucial role in the catalytic activity and electrical conductivity enhancement for Ti(3)C(2)based materials.