柳丽芬

个人信息Personal Information

教授

博士生导师

硕士生导师

主要任职:盘锦校区食品与环境学院副院长 Vice Dean School of Food and Environment Panjin Campus Dalian University of Technology

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工海洋与生命学院

学科:环境工程. 环境科学

办公地点:环境学院 B 505

化工 海洋与生命学院  D05-201

联系方式:0427-2631799;

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Facile synthesis of alloyed PtNi/CNTs electrocatalyst with enhanced catalytic activity and stability for methanol oxidation

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论文类型:期刊论文

发表时间:2021-01-10

发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS

卷号:120

ISSN号:1387-7003

摘要:Pt-based alloy electrocatalysts, PtNi/CNTs and PtNi, were synthesized through facile chemical reduction reaction for methanol oxidation reaction (MOR). Morphology, structure and composition of the PtNi/CNTs and PtNi electrocatalysts were physical characterized by the means of SEM, EDS, XRD and XPS. The catalytic activity, stability and durability of the obtained electrocatalysts were studied by cyclic voltammetry (CV) and amperrometric i-t cueves (i-t). The PtNi catalysts nanoparticles (NPs) obtained around 20 nm were homogenous distribution of two metal elements, and PtNi were well doped on the carbon nanotubes (CNTs) for PtNi/CNTs catalysts. The incorporation of Ni and high surface area of CNTs make the PtNi/CNTs and PtNi catalysts showing high eletrocatalytic activity for MOR. Furthermore, both PtNi/CNTs and PtNi electrocatalysts exhibit outstanding stability and durability at room temperature in acidic medium. This research provides positive guidance to prepare high performance and excellent stability electrocatalysts for MOR.