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Synthesis and characterization of novel poly(aryl ether sulfone ketone)s containing phthalazinone and biphenyl moieties

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Indexed by:期刊论文

Date of Publication:2008-02-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:SCIE、ISTIC

Volume:19

Issue:2

Page Number:227-229

ISSN No.:1001-8417

Key Words:poly(aryl ether sulfone ketone); phthalazinone; biphenyl; thermal property; solubility

Abstract:A novel series of poly(aryl ether sulfone ketone)s (PPESKs) containing phthalazinone and biphenyl moieties were prepared by two-step nucleophilic polycondensation reaction. The (M) over bar (W) values of these copolymers were between 38,330 and 67,900. The glass transition temperatures (T-g) and 5% decomposition temperatures were ranged in 253-269 degrees C and 488-500 degrees C, respectively, The structures of these copolymers were confirmed by FT-IR and H-1 NMR. Moreover, all the resultant copolymers were amorphous determined by wide angle X-ray diffraction (WAXD). (C) 2007 Xi Gao Jian. Published by Elsevier B.V on behalf of Chinese Chemical Society. All rights reserved.

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