Thermoregulated phase-separable RU3(CO)(12)/PETPP complex catalyst for hydrogenation of styrene
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发布时间:2019-10-22
论文类型:期刊论文
发表时间:2002-10-01
发表刊物:CHINESE CHEMICAL LETTERS
收录刊物:ISTIC、SCIE
卷号:13
期号:10
页面范围:1011-1012
ISSN号:1001-8417
关键字:thermoregulated phase-separable catalysis; hydrogenation; styrene; ruthenium
摘要:Thermoregulated phase-separable Ru-3(CO)(12)/PETPP (PETPP=P[p-C6H4O (CH2CH2O)(n) H](3), n=6) complex catalyst was first applied in the hydrogenation of styrene. Under the conditions: P(H-2)=2.0MPa, T=90degreesC, styrene could be completely transferred and the yield of ethylbenzene reached up to 99.5%. After simple decantation, the catalyst could be reused for ten times without decreasing in activity.
