Preparation of spherical MCM-41 in water-acetone media
发表时间：2019-03-11
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- 论文类型：
- 期刊论文
- 第一作者：
- Zhang J.-C.
- 通讯作者：
- Liu, M.; Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China; email: lium@dlut.edu.cn
- 合写作者：
- Liu M.,Song C.-S.,Guo X.-W.
- 发表时间：
- 2009-10-01
- 发表刊物：
- Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)
- 收录刊物：
- EI、Scopus
- 文献类型：
- J
- 卷号：
- 25
- 期号：
- SUPPL. 2
- 页面范围：
- 61-64
- ISSN号：
- 10018719
- 摘要：
- The mesoporous silica nanoparticles with controlled morphologies were prepared in water-acetone solvent. Further investigations showed that prolonging the reaction time led to an increase of the cell parameter; increasing the amount of ammonia solution resulted in an increase of pore diameter and decreases of pore volume and specific surface area, however, increasing the amount of CTAB made the pore volume and the specific surface area increased while the pore diameter almost kept intact. Interestingly, it is proved that the mesoporous silica obtained at the system composition of n(TEOS):n(CTAB):n(NH3(H2O): n(Acetone):n(H2O)=1:0.07:1.4:20:144 composed of virtual mixed nanospheres including solid and hollow, which were of regular and uniform size, being approximately 500 nm. Solid sphere has obvious radial pores, whereas hollow sphere has a mesoporous shell perforated by hexagonally-arrayed cylindrical nanochannels.
- 是否译文：
- 否
