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A green route to methyl acrylate and acrylic acid by an aldol condensation reaction over H-ZSM-35 zeolite catalysts

发表时间:2019-03-12
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论文类型:
期刊论文
第一作者:
Ma, Zhanling
通讯作者:
Zhu, WL; Liu, ZM (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian Natl Lab Clean Energy,iChEM, Dalian 116023, Peoples R China.
合写作者:
Ma, Xiangang,Liu, Hongchao,He, Yanli,Zhu, Wenliang,Guo, Xinwen,Liu, Zhongmin
发表时间:
2017-08-21
发表刊物:
CHEMICAL COMMUNICATIONS
收录刊物:
SCIE
文献类型:
J
卷号:
53
期号:
65
页面范围:
9071-9074
ISSN号:
1359-7345
摘要:
A one-step aldol condensation reaction to produce MA and AA is a green and promising strategy. Here, the aldol condensation reaction was first conducted with DMM and MAc over different types of zeolite catalysts. The H-ZSM-35 zeolite demonstrates excellent catalytic performance with a DMM conversion of 100% and a MA + AA selectivity of up to 86.2% and superior regeneration ability, with great potential for industrial operation.
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