CO2 hydrogenation to methanol on Pd-Cu bimetallic catalysts: H2/CO2 ratio dependence and surface species
发表时间：2025-06-03
点击次数：
- 第一作者：
- 王永忠
- 通讯作者：
- 王桂茹,张雄福,王波,刘海鸥,郭新闻,王祥生
- 发表时间：
- 2022-10-10
- 发表刊物：
- 大连理工大学学报
- 文献类型：
- J
- 期号：
- 5
- 页面范围：
- 540-545
- ISSN号：
- 1000-8608
- 摘要：
- The influence of synthesis method on the synthesis of Ti-SiZSM-5 zeolite and the mechanism of synthesis are studied. The synthesis process of Ti-SiZSM-5 zeolite using much cheaper raw materials such as silica sol, [Ti(H2O2)2+], TEAOH and HDA depends strongly on n(SiO2)/n(TiO2), n(Na2O)/n(SiO2) and n(TEAOH+HDA)/n(SiO2). It has been found that Ti-SiZSM-5 can only be obtained at high n(SiO2)/n(TiO2), low n(Na2O)/n(SiO2) in the synthesis hydrogel and the chemical composition of the synthesis hydrogel may be changed in a small range. Seed, structure-directing agent and the hydrogel ripening during the synthesis of Ti-SiZSM-5 zeolite are beneficial to the improvement of crystallinity and the incorporation of Ti into the framework of Ti-SiZSM-5.
- 备注：
- 新增回溯数据
- 是否译文：
- 否
