单波长可见光照射下二氧化碳羰基化反应研究
发表时间：2025-06-03
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- 第一作者：
- 庄建勤
- 通讯作者：
- 尹静梅,高大彬,郑学仿,周广运,周宁章,王祥生,郭新闻
- 发表时间：
- 2022-10-09
- 发表刊物：
- 高等学校化学学报
- 文献类型：
- J
- 卷号：
- 22
- 期号：
- 1
- 页面范围：
- 75-77
- ISSN号：
- 0251-0790
- 摘要：
- It is the first time to report the carbonylation of cyclohexene with carbon dioxide under ambient conditions irradiated at single wavelength visible light.The effects of catalysts,the additives and different wavelength have been investigated,which indicated that the metal complexes such as CoTPP and MnTPP acted as catalyst of the carbonylation as well as sensitizer under the irradiation of special wavelength visible light.Furthermore,when adding sodium proponiate to the solution,the catalysts such as PCFe would be activated and the formation of ester was promoted obviously.We also detected the quantum yield of this reaction,and found it can reach to 10-2.As far as the quantum yield and taking good advantage of the energy from solar was concerned.HSOsPCCo was the better catalyst for the carbonylation.
- 备注：
- 新增回溯数据
- 是否译文：
- 否
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