Facile synthesis of Fe-containing metal-organic frameworks as highly efficient catalysts for degradation of phenol at neutral pH and ambient temperature
发表时间：2019-03-09
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- 论文类型：
- 期刊论文
- 第一作者：
- Sun, Qiao
- 通讯作者：
- Sun, Q (reprint author), Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
- 合写作者：
- Liu, Min,Li, Keyan,Zuo, Yi,Han, Yitong,Wang, Junhu,Song, Chunshan,Zhang, Guoliang,Guo, Xinwen
- 发表时间：
- 2015-01-01
- 发表刊物：
- CRYSTENGCOMM
- 收录刊物：
- SCIE、Scopus
- 文献类型：
- J
- 卷号：
- 17
- 期号：
- 37
- 页面范围：
- 7160-7168
- ISSN号：
- 1466-8033
- 摘要：
- In this work, MIL-53(Fe) was synthesized using a solvothermal method under static conditions. However, it was interesting to find that another MIL-53 type material, Fe(BDC)(DMF,F), was obtained when stirring conditions were used while keeping the other conditions fixed. The Fe-containing metal-organic frameworks (MOFs) were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fe-57 Mossbauer spectrometry and thermogravimetric analysis (TGA). By simply increasing the crystallization time under agitation, the morphology of the Fe(BDC)(DMF,F) crystals went through a striking transition from a bulky irregular shape to a rod-like morphology. The catalytic performance of the Fe-MOFs was evaluated in the degradation of phenol solution at near neutral pH at 35 degrees C. A significantly better catalytic activity was achieved for Fe(BDC)(DMF,F) than for MIL-53(Fe) and NH2-MIL-53(Fe) due to the existence of Fe(II) in its framework. Phenol was almost completely decomposed in 3 hours, and the conversions of hydrogen peroxide and chemical oxygen demand (COD) were 74.1% and 78.7%, respectively.
- 是否译文：
- 否
