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One-pot synthesis-assembly-separation of cucurbit[6]uril via SO3H-functionalized ionic liquids

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Jiang, Xiao
通讯作者:
Liu, L (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
合写作者:
Li, Peipei,Liu, Xiumei,Guo, Xinwen,Liu, Li
发表时间:
2014-12-01
发表刊物:
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
收录刊物:
SCIE
文献类型:
J
卷号:
80
期号:
3-4
页面范围:
457-461
ISSN号:
0923-0750
关键字:
Supramolecular; Cucurbituril; Ionic liquid; Anion; Microwave
摘要:
A novel microwave-assisted route to synthesize cucurbit[n]uril in SO3H-functionalized ionic liquids was reported, which enabled the automatic separation of cucurbit[6]uril through anion assembly. For the first time, the route has realized synthesis-assembly-separation of cucurbit[6]uril in one pot. The reaction yield and separation efficiency can be tuned by choice of anionic groups in ionic liquids.
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