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Fabrication of hollow spheres by dry-gel conversion and its application in the selective hydrodesulfurization of FCC gasoline

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Zhang, Jinchang
通讯作者:
Song, CS (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, PSU DUT Joint Ctr Energy Res, Dept Catalysis Chem & Engn,Sch Chem Engn, Dalian 116024, Peoples R China.
合写作者:
Wang, Gang,Jin, Fengying,Fang, Xiangchen,Song, Chunshan,Guo, Xinwen
发表时间:
2013-04-15
发表刊物:
JOURNAL OF COLLOID AND INTERFACE SCIENCE
收录刊物:
SCIE、EI
文献类型:
J
卷号:
396
页面范围:
112-119
ISSN号:
0021-9797
关键字:
Hollow sphere; Dry-gel conversion; Selective hydrodesulfurization
摘要:
Hollow spheres were synthesized from MCM-41 solid spheres by dry-gel conversion: It was found that water amount has a major impact on the formation of hollow spheres. Transmission electron microscopy (TEM) images revealed that the hollow spheres are between 500 and 600 nm in size with a dense shell of ca. 100 nm. The synthesized hollow sphere sample was examined as a support for hydrodesulfurization catalyst. The sulfur removal was enhanced while olefin hydrogenation of FCC gasoline was suppressed, and thus, the octane value was preserved when the hollow spheres (Na type) were loaded with Ni and Mo oxides as catalyst. (C) 2013 Elsevier Inc. All rights reserved.
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