Mg Doping Effect on Nanoscale Crystallization and Band Gap of Sol-Gel Derived MgxZn1-xO (x=0-1) Alloys
发表时间：2019-03-09
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- 论文类型：
- 期刊论文
- 第一作者：
- Li, Keyan
- 通讯作者：
- Xue, DF (reprint author), Dalian Univ Technol, Sch Chem Engn, Dept Mat Sci & Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
- 合写作者：
- Wu, Junshu,Xue, Dongfeng
- 发表时间：
- 2011-06-01
- 发表刊物：
- NANOSCIENCE AND NANOTECHNOLOGY LETTERS
- 收录刊物：
- Scopus、SCIE、EI
- 文献类型：
- J
- 卷号：
- 3
- 期号：
- 3
- 页面范围：
- 417-422
- ISSN号：
- 1941-4900
- 关键字：
- Sol-Gel; MgxZn1-xO Alloys; Crystallization; Band Gap
- 摘要：
- A series of MgxZn1-xO (x = 0-1) alloyed powders with different Mg concentrations were crystallized by sol gel technique. Their morphological variation with increased Mg content was investigated by scanning electron microscopy (SEM). We found that the introduction of Mg2+ ions into ZnO matrix had significant influence on the crystallinity of highly Mg-incorporated alloys. In particular, different packing density and the interagglomeration of the nanoparticles give rise to textural nanosized pores in the pure ZnO spherical particles and pure MgO hollow shells. UV-visible (UV-Vis) absorption spectra indicate that Mg doping significantly increases the band gap of MgxZn1-xO alloys. Different alloyed crystals were also annealed in the range of 600-1000 degrees C to investigate their thermal stability and temperature-dependent optical properties, which indicates that the Mg concentration in the as-obtained alloys is a function of annealing temperature, thereby facilely tuning the band gap. These results suggest that MgxZn1-xO alloys have potential applications in a variety of optoelectronic devices.
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