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Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant

发表时间:2019-03-09
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论文类型:
期刊论文
第一作者:
Li, Shu Shuang
通讯作者:
Guo, XW (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China.
合写作者:
Zhang, An Feng,Liu, Min,Guo, Xin Wen
发表时间:
2011-03-01
发表刊物:
CHINESE CHEMICAL LETTERS
收录刊物:
SCIE、ISTIC
文献类型:
J
卷号:
22
期号:
3
页面范围:
303-305
ISSN号:
1001-8417
关键字:
Cationic organosilane surfactant; Hierarchical TS-1; Cyclohexene
摘要:
Hierarchical TS-1 has been synthesized in the presence of cationic organosilane surfactant. The material is characterized with XRD, TEM, N(2) adsorption isotherm. The results show that the hierarchical TS-1 aggregates consist of small primary units with sizes of 20-30 nm. The BET surface area increases from 420 to 513 m(2)/g compared to conventional TS-1 zeolite. The sample is shown to be more active in epoxidation of cyclohexene than conventional TS-1. (C) 2010 Xin Wen Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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