SO3H-functionalized ionic liquids for selective alkylation of p-cresol with tert-butanol
发表时间：2019-03-10
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- 论文类型：
- 期刊论文
- 第一作者：
- Liu, Xiumei
- 通讯作者：
- Guo, X (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China.
- 合写作者：
- Zhou, Jinxia,Guo, Xinwen,Liu, Min,Ma, Xiaoliang,Song, Chunshan,Wang, Chang
- 发表时间：
- 2008-08-06
- 发表刊物：
- INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
- 收录刊物：
- SCIE、EI、Scopus
- 文献类型：
- J
- 卷号：
- 47
- 期号：
- 15
- 页面范围：
- 5298-5303
- ISSN号：
- 0888-5885
- 摘要：
- The SO3H-functionalized ionic liquids were synthesized by using pyridine and 1,4-butane or 1,3-propane sulfone as the source and characterized by NMR and time-of-flight mass spectrometry. The acidity of the ionic liquids determined by the Hammett method is almost the same as that of a conventional acid, such as H2SO4. The catalytic performance of ionic liquids for the tert-butylation of p-cresol with tert-butanol was evaluated; by using the ionic liquids as catalysts at the optimum reaction conditions, 79% of the p-cresol conversion and 92% of the selectivity to 2-tert-butyl-p-cresol can be obtained. The spent ionic liquid can be recovered and recycled. The possible mechanism for this reaction system was discussed based on the reaction results and the ab initio calculation results.
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- 否
