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论文类型：期刊论文

发表时间：2013-03-01

发表刊物：OPTICAL MATERIALS

收录刊物：SCIE、EI

卷号：35

期号：5

页面范围：973-977

ISSN号：0925-3467

关键字：Polyoxometalates; Polyacrylamide; Fe2+ doping; Hybrid films; Photochromism

摘要：New hybrid films were synthesized by Fe2+ doping into polyoxometalates acid (POMs)/polyacrylamide (PAM) system, and the effect of Fe2+ doping on microstructure and photochromic properties was studied via transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectra (UV-vis) and X-ray photoelectron spectroscopy (XPS). The shape of molybdenumphosphoric acid (PMoA) particles changed from well dispersed sphere to irregular conglomeration. The vibrational spectra of FT-IR verified that the hydrogen bonding between PMoA and PAM was weakened after Fe2+ doping. The hybrid films exhibited a good photochromic property, which changed from colorless to blue under UV irradiation. The color change intensity of PMoA/PAM film was 2.56 times stronger than that of Fe2+/PMoA/PAM under the same condition. XPS results indicated that the amount of PMoA in photo-reductive reaction was decreased after Fe2+ doping, which resulted in the photochromic efficiencies weakened. (C) 2012 Elsevier B.V. All rights reserved.