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Leaching behaviour and environmental risk assessment of heavy metals from electronic solder in acidified soil
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论文类型: 期刊论文
发表时间: 2015-11-01
发表刊物: ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
收录刊物: SCIE、PubMed、Scopus
卷号: 22
期号: 22
页面范围: 17683-17690
ISSN号: 0944-1344
关键字: Electronic solder; ICP-MS; Acidified soil; Leaching
摘要: The leaching behaviour of Sn and Pb elements from eutectic SnPb solder of electronic waste in acidic soil was investigated through acidification with HCl-H2SO4 solution and compared with saline solution. The amounts of Sn and Pb elements leached, when subjected to acidic soil, are higher than those with saline soil. Evidence for the significantly preferential release of Sn into the leachate is provided; the galvanic couple accelerated such preferential release. Surface product analysis reveals the slight damage of SnPb in saline soil. Serious dissolution due to electrochemical reaction and a thick, porous PbSO4 surface layer are observed in acidified soil, suggesting more severe toxicity potential of Pb in soil rather than in water.

程从前

副教授   博士生导师   硕士生导师

任职 : 院长助理,中国腐蚀与防护学会高温专业委员会委员,中国机械工程学会理化检验分委员会委员,辽宁省化工学会腐蚀与防护专业委员会委员

性别: 男

毕业院校:大连理工大学

学位: 博士

所在单位:材料科学与工程学院

学科:材料学

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