Zhao Qidong   

senior experimentalist
Supervisor of Master's Candidates

Academic Titles: Senior Laboratory Technician (no recruitment of postgraduate)
Other Post: 实验教师(教学实验岗)

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Language:English
  • 中文

Paper Publications

Synthesis and characterization of Cu+/ MIL-100(Fe) with enhanced catalytic performance for NH3-SCR

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Indexed by:Journal Article

Date of Publication:2018-01-02

Journal:FERROELECTRICS

Included Journals:EI、SCIE

Volume:522

Issue:1

Page Number:20-28

ISSN:0015-0193

Key Words:DeNOx catalysts; selective catalytic reduction; Cu+; MIL-100(Fe); copper loading; MOFs; TB34; A

Abstract:A mesoporous MIL-100 (Fe) loaded with Cu+ species was synthesized using a hydrothermal method and its denitrification (deNOx) capability for NH3-SCR process was investigated. From X-Ray diffraction (XRD), hydrogen temperature programmed reduction (H-2 -TPR) and X-ray photoelectron spectroscopy (XPS) results, it was concluded that the Cu+ has been successfully introduced into the framework structure. Moreover, it was found that copper species play a significant role to promote NO reduction activity of Cu+/ MIL-100(Fe) and NO conversion increased with copper amount. Compared with MIL-100(Fe), Cu+/MIL-100(Fe) achieves a 16% increase in the maximum catalytic efficiency at 300 degrees C, suggesting a favorable interaction between metallic copper and iron active sites.

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