点击次数：

论文类型：期刊论文

发表时间：2016-04-01

发表刊物：INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

收录刊物：SCIE

卷号：11

期号：4

页面范围：3238-3259

ISSN号：1452-3981

关键字：Q235B steel; Cathodic protection; EIS; Effects of stress on corrosion behaviors

摘要：The separate and combined effects of cathodic protection potential and macro-elastic stress on corrosion behaviors of Q235B steel in an aerated 3.5% NaCl aqueous solution were investigated through measurements of corrosion potential, potentiodynamic polarization characteristics, potentiostatic current and electrochemical impedance spectra (EIS). Thermodynamic and kinetic analyses as well as experimental results show that the surface energy increment due to the elastic stress is sufficient to cause the negative direction shifted of the corrosion potential and enhance the corrosion rate of the steel significantly. The transfer resistance (R-ct) with different elastic stress levels and various cathodic polarization potentials was obtained by fitting the EIS data with the software ZSimpWin. The relationship between R-ct and cathodic polarization potential under different stress levels was also investigated. In the cathodic polarization region, both the optimum protection potential (E-opt) and hydrogen evolution potential (E-H) could be determined by the relationship curves of R-ct and cathodic polarization potential. The results indicate that R-ct decreases significantly with increasing of elastic stress, particularly near the optimum protection potential, and also the optimum protection potential decreases linearly with the increasing of elastic stress. Some concluding remarks achieved in this study provide important recommendations that the corrosion enhancement due to the elastic stress on structural surface should be considered in safety design of marine structures, and meanwhile provide an insight into the optimization of cathodic protection system design.