副教授 博士生导师 硕士生导师
任职 : 辽宁省能源材料及器件重点实验室副主任
性别: 男
毕业院校: 大连理工大学
学位: 博士
所在单位: 材料科学与工程学院
学科: 材料物理与化学. 材料表面工程
办公地点: 新三束4#楼311室
联系方式: 0411-84706661-101
电子邮箱: aimin@dlut.edu.cn
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论文类型: 期刊论文
发表时间: 2017-06-05
发表刊物: JOURNAL OF ALLOYS AND COMPOUNDS
收录刊物: SCIE、EI、Scopus
卷号: 706
页面范围: 401-408
ISSN号: 0925-8388
关键字: Alloy nanoparticle; Intermetallic compound; Arc-discharge plasma; Thermodynamic analysis; Anode; Lithium-ion battery
摘要: The electrochemical properties of Sn-M (M = Cu, Mg and Fe) bi-alloy nanoparticles prepared by DC arc-discharge method have been studied when these nanoparticles serve as the anode materials in Li-ion batteries (LIBs). Among all the alloy electrodes, the Sn-Fe electrode has the best initial specific capacity that maintains at about 227.3 mAh g(-1) within 20 cycles. The intermetallic compounds in the nanoparticles have been characterized and thermodynamics analysis is introduced to elucidate the energy balance of their formation mechanism. As the electrochemical behaviours of the various alloy nanoparticles are different, we conclude that the present intermetallic compounds eventually determine the lithium-ion storage ability as well as the cyclic stability during the lithiation/delithiation process. (C) 2017 Elsevier B.V. All rights reserved.