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论文类型：期刊论文

发表时间：2008-07-01

发表刊物：EUROPEAN PHYSICAL JOURNAL D

收录刊物：SCIE

卷号：48

期号：3

页面范围：365-373

ISSN号：1434-6060

摘要：The hydroxyl radical (OH) plays an important role in combustion systems, atmospheric chemistry and the removal of air pollutants by non- thermal plasmas. The present work reports the determination of the hydroxyl radicals in atmospheric dielectric barrier discharge plasmas via near infrared continuous wave cavity ring- down spectroscopy. The P-branches of OH X(2)Pi(i)(v' = 2 <- v '' = 0) bands were used forits number density measurements. The minimum measurable absorption coefficient is about 3 x 10(-8) cm(-1) in DBD plasmas. At certain experimental conditions (a. c. frequency of 70 kHz, 6700 ppm H(2)O in He, 1 atm), when the peak- to- peak discharge voltage varied from 6 kV to 10.4 kV, the determined OH radical concentration increased from (2.1 +/- 0.1) x 10(13) molecules cm(-3) to ( 3.7 +/- 0.1) x 10(13) molecules cm(-3). The plasma gas temperature, derived from the Boltzmann plots of OH rotational population distributions, ranged from 312 +/- 10 K to 363 +/- 10 K when the discharge voltage was raised in the above range. The in. uences of O(2) and N(2) addition on the production of OH radicals have been also investigated.