个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:校长助理
其他任职:精细化工国家重点实验室副主任,辽宁省低碳资源高值化利用重点实验室主任
性别:男
毕业院校:中科院山西煤化所
学位:博士
所在单位:化工学院
学科:工业催化. 化学工艺. 能源化工
办公地点:大连市凌工路2号大连理工大学西部校区化工楼,邮编:116024
联系方式:0411-84986112
电子邮箱:anhuilu@dlut.edu.cn
Hydroxyapatite nanowires rich in [Ca-O-P] sites for ethanol direct coupling showing high C6-12 alcohol yield
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论文类型:期刊论文
发表时间:2019-09-11
发表刊物:CHEMICAL COMMUNICATIONS
收录刊物:SCIE
卷号:55
期号:70
页面范围:10420-10423
ISSN号:1359-7345
摘要:Herein, we have shown that the [Ca-O-P] sites exposed on hydroxyapatite are clearly responsible for C-C formation in ethanol direct-coupling, and their high density accelerates the C-C coupling rate and boosts C6-12 alcohol production. Notably, nanowire-like hydroxyapatite exhibited 30.4% selectivity to n-butanol and 63.9% selectivity to C6-12OH at a conversion of 45.7% at 325 degrees C, and thereby close to 30% yield of C6-12OH, which is greatly higher than that using the state-of-the-art catalysts (6%).