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Indexed by:期刊论文

Date of Publication:2017-11-01

Journal:JOURNAL OF ENERGY CHEMISTRY

Included Journals:SCIE、EI

Volume:26

Issue:6

Page Number:1282-1290

ISSN No.:2095-4956

Key Words:Metal-organic aerogel; N-doped porous carbon; Lithium-sulfur batteries

Abstract:Nitrogen-doped three-dimensional (3D) porous carbon materials have numerous applications due to their highly porous structures, abundant structural nitrogen heteroatom decoration and low densities. Herein, nitrogen doped hierarchical 3D porous carbons (NHPC) were prepared via a novel metal-organic aerogel (MOA), using hexamethylenetetramine (HMT), 1,3,5-benzenetricarboxylic acid and copper (II) as starting materials. The morphology, porous structure of the building blocks in the NHPC can be tuned readily using different amount of HMT, which makes elongation of the pristine octahedron of HKUST-1 to give rise to different aspect ratio rod-like structures. The as-prepared NHPC with rod-like carbons exhibit high performance in lithium sulfur battery due to the rational ion transfer pathways, high N-doped doping and hierarchical porous structures. As a result, the initial specific capacity of 1341 mA h/g at rate of 0.5 C (1C = 1675 mA h/g) and high-rate capability of 354 mA h/g at 5C was achieved. The decay over 500 cycles is 0.08% per cycle at 1C, highlighting the long-cycle Li-S batteries. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.