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论文类型：期刊论文

发表时间：2015-12-01

发表刊物：CARBON

收录刊物：EI、SCIE、Scopus

卷号：95

页面范围：852-860

ISSN号：0008-6223

摘要：Nitrogen-doped porous carbons (NPCs) with high hydrogen sulfide (H2S) adsorption capacity have been prepared through the molten-salt approach, using D-glucose as carbon source, melamine as nitrogen source and eutectic salt (LiCl/KCl) as porogen. The NPCs possess tunable nitrogen content (3.07 - 24.31 wt.%) and specific surface area (451-1190 m(2)/g) with the changing of the weight ratio of nitrogen source to carbon source and synthesis temperature. The H2S adsorptive performance of NPCs is highly superior to that of non-doped porous carbon. X-rays photoelectron spectroscopy analyses combined with quantum chemical calculations demonstrate that the adsorption performance of the as-prepared NPCs depends on their nitrogen content and N-bonding configurations in the carbon materials, as well as their porosity. Pyridinic nitrogen doped carbon in NPCs have stronger interaction with H2S compared to pyrrolic and graphitic nitrogen doped carbon. Based on the advantages of the developed porosity and abundant nitrogen functional groups, the saturated sorption capacities of 0.97-1.25 mmol H2S/g can be achieved over NPCs at 25 degrees C under dry and anaerobic conditions. (C) 2015 Elsevier Ltd. All rights reserved.