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论文类型：期刊论文

发表时间：2016-05-04

发表刊物：DALTON TRANSACTIONS

收录刊物：SCIE、EI、PubMed

卷号：45

期号：18

页面范围：7708-7719

ISSN号：1477-9226

摘要：A series of novel laterally anchoring tetrahydroquinoline derivatives have been synthesized and investigated for their use in NiO-based p-type dye-sensitized solar cells. The kinetics of charge injection and recombination at the NiO-dye interface for these dyes have been thoroughly investigated using pico-second transient absorption and time-resolved infrared measurements. It was revealed that despite the anchoring unit being electronically decoupled from the dye structure, charge injection occurred on a sub picosecond timescale. However, rapid recombination was also observed due to the close proximity of the electron acceptor on the dyes to the NiO surface, ultimately limiting the performance of the p-DSCs.