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    杨希川

    • 研究员     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 电子邮箱:yangxc@dlut.edu.cn

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    High efficiency CdS quantum-dot-sensitized solar cells with boron and nitrogen co-doped TiO2 nanofilm as effective photoanode

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    论文类型:期刊论文

    发表时间:2015-07-01

    发表刊物:ELECTROCHIMICA ACTA

    收录刊物:SCIE、EI、Scopus

    卷号:169

    页面范围:103-108

    ISSN号:0013-4686

    关键字:CdS QD sensitized B/N co-doped TiO2 solar cell; B/N co-doped TiO2; NiS counter electrode; ((CH3)(4)N)(2)S/((CH3)(4)N)(2)S-n electrolyte

    摘要:The highly crystalline mesoporous B/N co-doped TiO2 nanomaterial is successfully synthetized using a facile process. A modified polysulfide redox couple, (CH3)(4)N)(2)S/((CH3)(4)N)(2)Sn, was employed in CdS quantum dots (QDs) sensitized B/N co-doped TiO2 solar cell with ZnS passivation layers and NiS as counter electrode, followed by chemical bath deposition (CBD) in an organic solution to prepare the QDs-cell to ensure high wettability and superior penetration ability of the B/N co-doped TiO2 films, then obtained an open-circuit photovoltage of 1.23 V, a high ff of 89%, a short-circuit photocurrent (J(sc)) of 4.46 mA cm (2), and yielding a high overall energy conversion of 4.88%. (C) 2015 Elsevier Ltd. All rights reserved.