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    杨希川

    • 研究员     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 电子邮箱:yangxc@dlut.edu.cn

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    Novel organic dyes with anchoring group of quinoxaline-2, 3-diol and the application in dye-sensitized solar cells

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    论文类型:期刊论文

    发表时间:2015-02-01

    发表刊物:DYES AND PIGMENTS

    收录刊物:SCIE、EI

    卷号:113

    页面范围:581-587

    ISSN号:0143-7208

    关键字:DSSCs; Organic sensitizers; Quinoxaline-2, 3-diol; Anchoring group; FTIR; Hydroxyl group

    摘要:Two organic quinoxaline dyes (WQ-1 and WQ-2) with a structure of quinoxaline-2, 3-diol as the electron withdrawing and anchoring group were synthesized and applied in the dye-sensitized solar cells. Fourier transform infrared spectroscopy and two other reference dyes (WQ-R1 and WQ-R2) without the hydroxyl groups were introduced to ascertain the adsorption properties of the dye series. The effect of the new electron acceptor and anchoring group on the performance of solar cells was investigated systematically. Under the standard light illumination (100 mW m(-2)), WQ-2 got an efficiency of 2.25%, with a short circuit photocurrent density of 5.51 mA cm(-2), an open circuit voltage of 0.612 V and a fill factor of 66.74%. (C) 2014 Elsevier Ltd. All rights reserved.