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    杨希川

    • 研究员     博士生导师 硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
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    论文成果

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    Molecular engineering of small molecules donor materials based on phenoxazine core unit for solution-processed organic solar cells

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      发布时间:2019-03-09

      论文类型:期刊论文

      发表时间:2014-07-21

      发表刊物:JOURNAL OF MATERIALS CHEMISTRY A

      收录刊物:Scopus、EI、SCIE

      卷号:2

      期号:27

      页面范围:10465-10469

      ISSN号:2050-7488

      摘要:A D-pi-A type small molecule POZ4 and a A-pi-D-pi-A type small molecule POZ6, in which phenoxazine was used as the central building block and dicyanovinyl was employed as the electron-withdrawing end-group, have been designed and synthesized. Compared with D-pi-A type donor material POZ4, the donor material POZ6 with A-pi-D-pi-A configuration shows much wider response to solar light. An efficiency of 5.60% was obtained for the POZ6: PC71BM based solar cells, and the device fabricated with POZ6:PC71BM (1 : 1) showed a much better balanced hole and electron mobility of 2.24 x 10(-4) cm(2) V-1 s(-1) and 3.17 x 10(-4) cm(2) V-1 s(-1), respectively.