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    杨希川

    • 研究员     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 电子邮箱:yangxc@dlut.edu.cn

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    Co-sensitization of Organic Dyes for Efficient Dye-Sensitized Solar Cells

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    论文类型:期刊论文

    发表时间:2013-01-01

    发表刊物:CHEMSUSCHEM

    收录刊物:SCIE、EI、PubMed、Scopus

    卷号:6

    期号:1

    页面范围:70-77

    ISSN号:1864-5631

    关键字:cyanines; dyes; pigments; sensitizers; solar cells

    摘要:Novel cyanine dyes, in which a tetrahydroquinoline derivative is used as an electron donor and 1-butyl-5-carboxy-3, 3-dimethyl-indol-1-ium moiety is used as an electron acceptor and anchoring group, were designed and synthesized for application in dye-sensitized solar cells. The photovoltaic performance of these solar cells depends markedly on the molecular structure of the dyes in terms of the n-hexyl chains and the methoxyl unit. Retardation of charge recombination caused by the introduction of n-hexyl chains resulted in an increase in electron lifetime. As a consequence, an improvement of open-circuit photovoltage (Voc) was achieved. Also, the electron injection efficiencies were improved by the introduction of methoxyl moiety, which led to a higher short-circuit photocurrent density (Jsc). The highest average efficiency of the sensitized devices (?) was 5.6?% (Jsc=13.3 mA?cm-2, Voc=606 mV, and fill factor FF=69.1?%) under 100 mW?cm-2 (AM 1.5G) solar irradiation. All of these dyes have very high absorption extinction coefficients and strong absorption in a relatively narrow spectrum range (500650 nm), so one of our organic dyes was explored as a sensitizer in co-sensitized solar cells in combination with the other two other existing organic dyes. Interestingly, a considerably improved photovoltaic performance of 8.2?% (Jsc=20.1 mA?cm-2, Voc=597 mV, and FF=68.3?%) was achieved and the device showed a panchromatic response with a high incident photon-to-current conversion efficiency exceeding 85?% in the range of 400700 nm.