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    杨希川

    • 研究员     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 电子邮箱:yangxc@dlut.edu.cn

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    Molecular Design to Improve the Performance of Donor-p Acceptor Near-IR Organic Dye-Sensitized Solar Cells

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    论文类型:期刊论文

    发表时间:2011-11-18

    发表刊物:CHEMSUSCHEM

    收录刊物:SCIE、PubMed、EI、Scopus

    卷号:4

    期号:11

    页面范围:1601-1605

    ISSN号:1864-5631

    关键字:aggregation; dyes; photophysics; sensitizers; solar cells

    摘要:Near-dye experience: Long, flexible carbon chains in the lateral anchoring groups of the donor part of a donor-π acceptor organic dye increase the power conversion efficiency dramatically. This performance enhancement can be ascribed to the prevention of the formation of molecular aggregates on the semiconductor nanoparticles, resulting in a lower recombination rate between transported electrons and I3-ions. A cell based on the new dye, HY113, gives a maximum IPCE value of 93% at 660nm. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.