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发布时间:2023-04-27
发表时间:2022-10-09
发表刊物:分子科学学报
所属单位:环境学院
卷号:28
期号:6
页面范围:457-461
ISSN号:1000-9035
摘要:The palladium-catalyzed direct 1,4-addition of arylhalides to
a,beta-Unsaturated ketones was in-vestigated. It was found that
Pd(PPh_3)_4 exhibited the highest catalytic activity to give the desired
1,4-addition products in satisfactory yields. The present method avoids
the use of expensive N-heterocyclic carbene ligands and organometallic
reagents,and has advantages of high selectivity and ease of opera-tion.
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