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论文类型：期刊论文

第一作者：Zhang, Xiaodong

通讯作者：Qu, ZP (reprint author), Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Linggong Rd 2, Dalian 116024, Peoples R China.

合写作者：Qu, Zhenping,Yu, Fangli,Wang, Yi,Zhang, Xin

发表时间：2013-04-01

发表刊物：JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

收录刊物：SCIE、EI

卷号：370

页面范围：160-166

ISSN号：1381-1169

关键字：Ag/SBA-15; CO oxidation; Pretreatment atmosphere; Ag loading

摘要：The structural properties of Ag/SBA-15 catalysts with various Ag loading after pretreatment under different atmosphere, i.e., O-2, Ar and H-2, in relation to their activities on CO oxidation were investigated. N-2 adsorption-desorption results showed that the pretreatment atmosphere had a negligible effect on the physical structure of all catalysts. Interestingly, it was found that different pretreatment atmosphere (Ar, O-2) and Ag loading exhibited a large difference on the structure of silver catalyst and their catalytic activity. For Ag/SBA-15 catalyst with low silver loading (<= 6 wt%), Ar pretreatment resulted in the highest activity for CO oxidation. However, the highest catalytic performance was observed after oxygen pretreatment over the silver catalyst with high loading (>6 wt%). UV-vis and H-2-TPR results showed Ar pretreatment and Ag loading strongly affected the states of Ag species for the silver catalysts, which were changed from metal Ag (<= 4wt%) to a mixture of Ag and Ag2O (>= 6 wt%). Moreover Ar pretreatment was favorable for the formation of small Ag particles for Ag/SBA-15 catalyst with low Ag loading. When the silver loading is increased, the heavy aggregation of silver particles occurred after Ar pretreatment, resulting in the decrease of TOF for CO oxidation. O-2 pretreatment was conductive to the formation of subsurface oxygen species on the larger silver particles for Ag/SBA-15 catalyst with high Ag loading, which resulted in the increase of TOF for CO oxidation. It was evident that small metal Ag particles was key factor of the higher catalytic activity for Ag/SBA-15 catalyst with low Ag loading, while a large number of subsurface oxygen species played an important effect on the higher catalytic activity for Ag/SBA-15 catalyst with high Ag loading. (C) 2013 Elsevier B.V. All rights reserved.