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    张新

    • 工程师      
    • 性别:女
    • 毕业院校:大连理工大学
    • 学位:硕士
    • 所在单位:环境学院
    • 学科:有机化学. 环境工程
    • 电子邮箱:xinzhang@dlut.edu.cn

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    Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide

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    论文类型:期刊论文

    第一作者:Peng, Xiu Juan

    通讯作者:Peng, XJ (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China.

    合写作者:Yan, Mei,Zhang, Xin,Bao, Ming

    发表时间:2011-06-01

    发表刊物:CHINESE CHEMICAL LETTERS

    收录刊物:SCIE、ISTIC、CSCD

    卷号:22

    期号:6

    页面范围:643-646

    ISSN号:1001-8417

    关键字:SBA-15-supported palladium catalyst; Heck reaction; Supercritical carbon dioxide

    摘要:A new method for the preparation of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide was presented. The newly formed SBA-15-supported palladium catalyst (Ph-SBA-15-PPh(3)-Pd) exhibited high catalytic activity for the Heck reaction of 4-nitrobromobenzene with methyl acrylate. The catalyst can be reused several times without a loss of activity. (C) 2011 Xiu Juan Feng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.