Hits:

Indexed by:期刊论文

Date of Publication:2009-04-02

Journal:THIN SOLID FILMS

Included Journals:SCIE、EI

Volume:517

Issue:11

Page Number:3304-3309

ISSN No.:0040-6090

Key Words:Cr-Ni-N; Magnetron sputtering; Nano-hardness; Tribological coatings; Wear; X-ray diffraction; Scanning electron microscopy

Abstract:Cr-Ni-N coatings were deposited on 304 stainless steel substrates using a conventional direct current magnetron reactive sputtering system in nitrogen-argon reactive gas mixtures. The influence of Ni content (0 <= x <= 20 at.%) on the coating composition, microstructure, and tribological properties was investigated by glow discharge optical spectroscopy, X-ray diffraction and transmission electron microscopy, scanning electron microscopy (SEM), nano-indentation, and pin-on-disk tests. The results showed that microstructure and properties of coatings changed due to the introduction of Ni. The ternary Cr-Ni-N coatings exhibited solid solution Structures in spite of the different compositions. The addition of Ni strongly favoured preferred orientation growth of < 200 >. This preferred orientation resulted from the formed nano-columns being composed of grains with the same crystallographic orientation, as confirmed by SEM cross-sectional observations. The mechanical properties including the nano-hardness and reduced Young's modulus decreased with increasing Ni content. Pin-on-disk tests showed that low Ni content coatings presented higher abrasion resistance than high Ni content coatings. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.