点击次数：

论文类型：期刊论文

发表时间：2005-01-01

发表刊物：5th Pacific Rim International Conference on Advanced Materials and Processing

收录刊物：SCIE、CPCI-S、Scopus

卷号：475-479

期号：V

页面范围：3381-3384

ISSN号：0255-5476

关键字：bulk metallic glasses; Cu-Zr-Al alloys; atomic cluster structure; electron concentration

摘要：The present paper covers in a comprehensive manner the formation of the Cu-based Cu-Zr-Al bulk metallic glasses (BMGs). Composition optimization for BMG formation is realized by using an "e/a-variant criterion". This criterion is incorporated into the ternary phase diagram by a straight composition line, which is defined by linking a specific binary composition to the third element. There e/a-variant composition lines are constructed: (Cu9Zr4)(1-x)Al, (Cu61.8Zr38.2)(1-x)Al-x and (Cu56Zr44)(1-x)Al-x, where Cu9Zr4, Cu61.8Zr38.2 and Cu56Zr44 are specific cluster compositions in the Cu-rich Cu-Zr binary system. No Cu-based BMGs are obtained in the composition line (Cu9Zr4)(1-x)Al-x using our suction casting techniques, while BMGs are obtained within an e/a span from 1.24 to 1.3 and from 1.28 to 1.36 respectively along the other two lines (Cu61.8Zr38.2)(1-x)Al-x and (Cu56Zr44)(1-x)Al-x. Thermal analysis results indicate that the BMGs on every composition line manifest increased thermal stability and glass forming ability (GFA) with increasing e/a ratios. The maximum appears in Cu58.1Zr35.9Al6 with the e/a value of 1.3, which belongs to the (Cu61.8Zr38.2)(1-x)Al-x series. The characteristic thermal parameters of this BMG are T-g = 760K, T-g/T-m = 0.659 and T-g/T-l = 0.648, which are all superior to those reported for the known Cu55Zr40Al5 BMG.