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论文类型：期刊论文

发表时间：2013-07-01

发表刊物：SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY

收录刊物：SCIE、EI

卷号：56

期号：7

页面范围：1419-1422

ISSN号：1674-7348

关键字：Ti-based alloy; bulk metallic glasses; cluster-plus-glue-atom model; glass forming ability

摘要：Bulk amorphous formation in Ti-Cu-based multicomponent alloys, free of Ni, Pd and Be elements, were studied using the cluster-plus-glue-atom model. The basic cluster formula was revealed as [Ti9Cu6]Cu-3 to explain the best binary glass forming composition Ti50Cu50=Ti9Cu9, where the CN14 rhombi-dodecahedron Ti9Cu6 was the principal cluster in the devitrification phase CuTi. This basic cluster formula was further alloyed with Zr and Sn and a critical glass forming ability was reached at (Ti7.2Zr1.8)(Cu8.72Sn0.28) and (Ti7.2Zr1.8)(Cu8.45Sn0.55) up to 5 mm in diameter by suction casting, which was the largest in Ti-Cu-based and Ni-, Pd- and Be-free alloys.