论文成果
The delta-Al4Cu9 phase as an approximant of quasicrystals
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  • 论文类型:期刊论文
  • 发表时间:1996-06-01
  • 发表刊物:PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES
  • 收录刊物:SCIE、Scopus
  • 文献类型:J
  • 卷号:73
  • 期号:6
  • 页面范围:1519-1528
  • ISSN号:0141-8610
  • 摘要:This paper analyses the structural properties of the delta-Al4Cu9 phase as an approximant to quasicrystals. The discussion is developed along two directions. One is the valence electron concentration (VEC) correlation; both the delta-Al4Cu9 and Al-Cu-Fe icosahedral phases are Hume-Rothery intermetallics with similar values of VEC per unit volume. The other is atomic structural resemblance analysis; delta-Al4Cu9 can be viewed either as six-layer stacking of flat and puckered layers along one [110] direction or as parallel pentagonal columns aligned along the same direction. It is also pointed out that vacancy sites play two important roles: to regulate a relatively constant VEC per unit volume and to facilitate the formation of basic pentagonal configurations.

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