论文成果
W alpha Mn1-alpha Ox Catalysts Synthesized by a One-Step Urea Co-precipitation Method for Selective Catalytic Reduction of NO with NH3 at Low Temperatures
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- 论文类型：期刊论文
- 发表时间：2016-03-01
- 发表刊物：5th Sino-Australian Symposium on Advanced Coal and Biomass Utilisation
Technologies
- 收录刊物：SCIE、EI、CPCI-S
- 文献类型：J
- 卷号：30
- 期号：3
- 页面范围：1810-1814
- ISSN号：0887-0624
- 摘要：Selective catalytic reduction (SCR) of NOx with NH3 (NH3-SCR) at low temperatures is a promising technology for DeNOx (removal of NOx) as a result of its high NOx conversion, excellent selectivity, and broad application prospect. As a result of the remarkable activity under low temperature for SCR performance, Mn-based catalysts have attracted extensive attention. In this work, a series of WaMn1 - aOx (a = 0, 0.25, 0.33, 0.5, or 1) catalysts were synthesized by a one-step urea co-precipitation method and characterized by X-ray diffraction, Raman, X-ray photoelectron spectroscopy, thermogravimetric analysis, and scanning electron microscopy. Thereamong, the W0.33Mn0.66Ox catalyst showed the highest NH3-SCR activity within a broad temperature range of 230-470 degrees C. In addition, the active Mn and W species were in highly amorphous or poorly crystalline states. It was revealed that the interaction of W and Mn increased the chemistry oxygen content of the catalysts, thus enhancing the low-temperature SCR performance.
