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论文类型：期刊论文

发表时间：2017-06-13

发表刊物：INTEGRATED FERROELECTRICS

收录刊物：SCIE、EI、Scopus

卷号：181

期号：1

页面范围：14-25

ISSN号：1058-4587

关键字：Selective catalytic reduction; Mesoporous iron trimesate catalyst; activation temperature and Eley-Rideal mechanism

摘要：A mesoporous iron trimesate MIL-100(Fe) with mixed Fe-III/Fe-II states was successfully employed for selective catalysis reduction with ammonia (NH3-SCR) reaction. The important role played by activation temperature were experimentally evidenced. It was found that the sample dried under vacuum at 473 K for 12 h yielded 100% NO conversion at 300 degrees C. MIL-100(Fe) was characterized by X-ray diffraction, scanning electron microscopy, N-2 adsorption, Fourier-transform infrared spectroscopy and thermal analysis. In situ Fourier-transform infrared spectroscopy revealed that NO could obviously adsorb on the Lewis-acid site of MIL-100(Fe), which contributed to the NH3-SCR reaction following Eley-Rideal (E-R) mechanism. In addition, the reusability of MIL-100(Fe) catalyst was also evaluated.