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论文类型：期刊论文

发表时间：2003-01-01

发表刊物：NEW JOURNAL OF CHEMISTRY

收录刊物：SCIE

卷号：27

期号：8

页面范围：1264-1269

ISSN号：1144-0546

摘要：The structure, physical characteristics and selective photocatalytic oxidation properties of quantum confined nanosize iron doped TiO2 (Q-TiO2/Fe3+) particles were studied by TG-DSC, XRD, DRS, EPR and Selective Oxidation Photocatalytic Measurements. It is shown that the solubility of iron in the obtained Q-TiO2/Fe3+ nanoparticles is 1.0 atom% and the iron doping level has a great influence on the transformation of anatase to rutile (A-R). The quantum confined effect was observed for Q-TiO2/Fe3+ nanoparticles. All of the samples have EPR Bulk-Fe3+ and Surf-Fe3+ signals, which are located in the bulk and surface of TiO2 nanoparticles respectively. Quantitative EPR results indicate that the relative EPR intensity of these paramagnetic centers shows regular change with varying corresponding iron modi. cation level. In situ EPR indicates that the photo-generated charge carrier (h(+), e(-)) could be trapped by different Fe3+ sites simultaneously, i.e., trapping of h(+) is due to Surf-Fe3+ sites at g = 4.30, whereas that of e(-) is attributed to Bulk-Fe3+ sites at g = 1.99. Selective photocatalytic oxidation of cyclohexane into cyclohexanol with higher selectivity has been obtained by molecular oxygen activation over Q-TiO2/Fe3+ nanoparticles under mild conditions. It is thought that the optical surface state of Q-TiO2/Fe3+ nanoparticles play a key role in the selective photocatalytic oxidations.