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论文类型：期刊论文

发表时间：2012-07-01

发表刊物：APPLIED SURFACE SCIENCE

收录刊物：SCIE、EI

卷号：258

期号：18

页面范围：7099-7104

ISSN号：0169-4332

关键字：alpha-Fe2O3 microparticles; Hollow structure; Optical properties; Surface photovoltage

摘要：Hematite (alpha-Fe2O3) particles with hollow spindle-shaped microstructure were successfully synthesized by a one-pot hydrothermal approach in large scale. The structural properties of the sample were systematically investigated by X-ray powder diffraction, scanning electron microscopy, energy-dispersive X-ray spectrum, high resolution transmission electron microscopy, selected-area electron diffraction techniques, UV-vis diffuse reflectance spectroscopy and infrared spectroscopy techniques. The characterization results revealed that the alpha-Fe2O3 microparticles with a single-domain crystalline structure was mainly grown along the (1 0 4) crystal plane. The valence states and the surface chemical compositions of alpha-Fe2O3 were further identified by X-ray photoelectron spectroscopy. The feature of photo-induced charge separation on spectrum was demonstrated by the surface photovoltage measurement under different external biases. The observed photoelectric characteristics of the as-fabricated material are beneficial for various optical and electronic applications. (C) 2012 Elsevier B.V. All rights reserved.