点击次数：

论文类型：期刊论文

发表时间：2011-07-29

发表刊物：SEPARATION AND PURIFICATION TECHNOLOGY

收录刊物：SCIE、EI

卷号：80

期号：2

页面范围：345-350

ISSN号：1383-5866

关键字：SO2 removal; NiAl mixed oxides; Adsorption

摘要：A series of NiAl mixed oxides derived from hydrotalcite-like compounds were prepared by a urea hydrolysis method, and characterized by TGA, XRD, SEM, CO2-TPD, N-2 adsorption/desorption and XPS techniques. The SO2 adsorption capacity of the materials correlated closely with their basicity and active oxygen species on the surface, as estimated by a volumetric method. The NiAl mixed oxide with the optimal Ni/Al molar ratio of 3 showed the best performance of SO2 adsorption. Moreover, its adsorption equilibrium of a type I isotherm and pore opening in the quasi-micropore region significantly improve the adsorption performance for low-concentration SO2. (C) 2011 Elsevier B.V. All rights reserved.