李新勇

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:中国科学院兰州化学物理研究所

学位:博士

所在单位:环境学院

办公地点:环境楼 B415

联系方式:Tel: 0411-84706658

电子邮箱:xyli@dlut.edu.cn

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Selective oxidation of cyclopentene catalyzed by Pd(CH3COO)(2)-NPMoV tinder oxygen atmosphere

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论文类型:期刊论文

发表时间:2008-09-01

发表刊物:REACTION KINETICS AND CATALYSIS LETTERS

收录刊物:EI、SCIE、Scopus

卷号:94

期号:2

页面范围:191-198

ISSN号:0133-1736

关键字:cyclopentene; cyclopnetanone; Pd(CH3COO)(2); NPMoV

摘要:The selective oxidation of cyclopentene to cyclopentanone catalyzed by Pd(CH3COO)(2)-NPMoV was investigated under atmospheric oxygen in aqueous acetonitrile acidified by CH3SO3H. It was shown that the conversion of cyclopentene and the yield of cyclopentanone was nearly 100% and 94.6%, respectively, under the optimized reaction condition.