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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理
办公地点：化工实验楼a段308
联系方式：hanli@dlut.edu.cn
电子邮箱：hanli@dlut.edu.cn
Facile Synthesis of DendriMac Polymers via the Combination of Living Anionic Polymerization and Highly Efficient Coupling Reactions
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论文类型：期刊论文
发表时间：2016-01-01
发表刊物：MACROMOLECULAR RAPID COMMUNICATIONS
收录刊物：EI、PubMed、SCIE、Scopus
卷号：37
期号：2
页面范围：168-173
ISSN号：1022-1336
关键字：building of polymeric bricks; click chemistry; hydrosilylation; living anionic polymerization; synthesis of dendrimac polymers
摘要：Two DendriMac polymers (Dendri-hydr and Dendri-click) are efficiently and conveniently synthesized via the combination of living anionic polymerization (LAP) and hydrosilylation/click chemistry. Based on the end-capping of DPE derivatives (DPE-SiH and DPE-DA) toward polymeric anions, the polymeric core and arms are effectively synthesized, and the base polymers can be regarded as polymeric bricks. Hydrosilylation and click chemistry are used as coupling reactions to construct the DendriMac polymers with high efficiency and convenience. The numbers of branched arms are calculated by SEC as 5.84 and 6.08 for Dendrihydr and Dendri-click, respectively, which indicate that the DendriMac architectures exhibit high structural integrity. Because of its independence, high efficiency, and convenience, the whole construction can be regarded as the "building of polymeric bricks."
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