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论文类型：期刊论文

发表时间：2015-09-01

发表刊物：BIORESOURCE TECHNOLOGY

收录刊物：SCIE、EI、PubMed、Scopus

卷号：192

页面范围：592-602

ISSN号：0960-8524

关键字：Oil-plant wastes; Pyrolysis; TGA; Fixed-bed reactor; Coats-Redfern approach

摘要：Pyrolysis characteristics of four distinct oil-plant wastes were investigated using TGA and fixed-bed reactor coupled with GC. TGA experiments showed that the pyrolysis behaviors were related to biomass species and heating rates. As the heating rate increased, TG and DTG curves shifted to the higher temperatures, and the comprehensive devolatilization index obviously increased. The remaining chars from TGA experiments were higher than those obtained from the fixed-bed experiments. The crack of tars at high temperatures enhanced the formation of non-condensable gases. During the pyrolysis, CO and CO2 were the major gases. Chars FTIR showed that the functional groups of O-H, C-H-n, C=O, C-O, and C-C gradually disappeared from 400 degrees C on. The kinetic parameters were calculated by Coats-Redfern approach. The results manifested that the most appropriate pyrolysis mechanisms were the order reaction models. The existence of kinetic compensation effect was evident. Crown Copyright (C) 2015 Published by Elsevier Ltd. All rights reserved.