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论文类型：期刊论文

发表时间：2008-11-01

发表刊物：ENERGY & FUELS

收录刊物：SCIE、EI、Scopus

卷号：22

期号：6

页面范围：3944-3948

ISSN号：0887-0624

摘要：On a semi-continuous apparatus, a weakly reductive Shenfu-Dongsheng (SD) coal and a reductive Pingshuo (PS) coal were non-isothermally extracted with sub- and supercritical water to explore the differences between the two coals. The effect of the temperature on the extract formation rate, conversion, and product composition under different pressures was investigated. The extraction results of two coal samples indicate that the extract formation rate has a maximum in the studied temperature range between room temperature and 500 degrees C. The temperature corresponding to the maximum extract formation rate, changing with the pressure, is between 390 and 410 degrees C. The gas yield, extract yield, and conversion of two coals increase with the increasing pressure. In comparison to PS coal, SD coal has a low temperature corresponding to the maximum extract formation rate under the same pressure. Both coals have a main fraction of asphaltene, but SD coal has a higher fraction of oil than PS coal. The main gas components are CO(2), CH(4), and H(2). The gas from PS coal has a higher CH4 content and lower CO(2) content than that from SD coal. The analysis results of the extraction residue indicated that SD coal has a low residue yield and the residue shows a large surface area and small average pore diameter compared to PS coal.