Indexed by:
Journal Papers
First Author:
Zhou, Xiaohu
Correspondence Author:
Dong, WR; Yang, XM (corresponding author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China.; Yang, XM (corresponding author), Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China.
Co-author:
Liu, Yiqiang,Chen, Yang,Li, Xinyong,Xiao, Chunlei,Dong, Wenrui,Yang, Xueming
Date of Publication:
2020-07-30
Journal:
JOURNAL OF PHYSICAL CHEMISTRY A
Included Journals:
SCIE
Document Type:
J
Volume:
124
Issue:
30
Page Number:
6125-6132
ISSN No.:
1089-5639
Abstract:
Hydrofluoroolefins (HFOs, CxF2x+1CH=CH2) have great potential to replace hydrofluorocarbons (HFCs) as refrigerants. Here the kinetics for the reaction of syn-CH3CHOO with CF3CH=CH2 (HFO-1243zf), the simplest of HFOs, have been studied in a flash photolysis flow reactor at a total pressure of 50 Torr, by using the OH laser-induced fluorescence (LIF) method. The bimolecular reaction rate coefficients were measured at temperatures ranging from 283 to 318 K. A weak positive temperature dependence was observed, with an activation energy of 1.41 +/- 0.12 kcal mol(-1). At 298 K, the measured rate coefficient was (2.42 +/- 0.51) x 10(-14) cm(3) s(-1), in the vicinity of the previously reported upper limit value for the reaction of CH2OO with CF3CH=CH2.
Translation or Not:
no
