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论文类型：期刊论文

发表时间：2021-12-14

发表刊物：CHEMICAL ENGINEERING SCIENCE

卷号：207

页面范围：1096-1106

ISSN号：0009-2509

关键字：Gas hydrate; Water migration; Carbon dioxide; Propane

摘要：Hydrate-induced water migration is an unusual behaviour that occurs in certain hydrate formation processes, such as in the formation of propane-containing hydrate. This study is the first to investigate the continuous, staged processes of constant-volume formation, constant-pressure reformation and exhaust dissociation of CO2-C3H8 hydrates using the magnetic resonance imaging (MRI) technique. Real-time MRI images indicate that the formation of CO2-C3H8 hydrates draw water from its surroundings, causing the local water saturation to increase. As the concentrated water can further form hydrates and extend to the gas phase, the water appears as though it climbs upward through the glass sand and hydrate zone towards the gas phase. Experiments under different formation pressures indicate that the locations of hydrate-induced water migration are uncertain and depend on hydrate nucleation. The evolution processes of hydrate-induced water migration under different initial pressures have good similarity. In addition, water migration will still occur during the reformation stage. The initial pressure has great effects on both the formation and dissociation of hydrate. In addition, faster dissociation may make the water move upward due to strong gas release. The findings in this study are significant to future research on propane-containing hydrate, especially for hydrate-based seawater desalination applications. (C) 2019 Elsevier Ltd. All rights reserved.