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个人信息Personal Information
研究员
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化学学院
学科：无机化学
办公地点：主校区海映楼514
电子邮箱：xjing@dlut.edu.cn
A bi-functional luminescent Zn(II)-MOF for detection of nitroaromatic explosives and Fe3+ ions
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论文类型：期刊论文
发表时间：2018-03-01
发表刊物：SENSORS AND ACTUATORS B-CHEMICAL
收录刊物：SCIE、EI
卷号：257
页面范围：207-213
ISSN号：0925-4005
关键字：Metal-organic framework; Nitroaromatic compounds; Fe3+ ions; Highly sensitive
摘要：A luminescent Zn(II) metal-organic framework (MOF), [Zn-3(L)(2)(bipy)(mu(3)-OH)(2)]center dot 3H(2)O (1) (bipy = 4,4'-bipyridine, H2L = 9H-carbazolyl-3,6-dicarboxylic acid) was obtained by the reaction of a rigid ligand H2L and Zn(II) ions. Compound 1 possesses an interesting 3D network with [Zn-9(mu(3)-OH)(6)(CO2)(12)] units as eighteen-connected nodes. Particularly, 1 shows highly sensitive response to nitroaromatic compounds (NACs) and Fe3+ ions through fluorescence quenching. At the same time, 1 can be easily recycled by washing with N, N'-dimethylformamide (DMF) or distilled water after sensing studies, indicating that it can be reused easily. Furthermore, the possible detection mechanisms have also been discussed. (C) 2017 Elsevier B.V. All rights reserved.