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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本冈山大学
学位：博士
所在单位：化工学院
学科：精细化工. 应用化学
办公地点：大连理工大学西部校区E209
联系方式：13591789942
电子邮箱：jncui@dlut.edu.cn
Ratiometric fluorescent and colorimetric sensors for Cu2+ based on 4,5-disubstituted-1,8-naphthalimide and sensing cyanide via Cu2+ displacement approach
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论文类型：期刊论文
发表时间：2010-02-27
发表刊物：TETRAHEDRON
收录刊物：SCIE、Scopus
卷号：66
期号：9
页面范围：1678-1683
ISSN号：0040-4020
关键字：Ratiometric; Fluorescent; Colorimetric; Cu2+; Naphthalimide; Cyanide
摘要：Two 4,5-disubstituted-1,8-naphthalimide derivatives 1 and 2 were synthesized as ratiometric fluorescent and colorimetric sensors for Cu2+, respectively In 100% aqueous solutions of 1, the presence of Cu2+ induces a strong and increasing fluorescent emission centered at 478 nm at the expense of the fluorescent. emission of 1 centered at 534 rim Compound 2 senses Cu2+ by means of a colorimetric (primrose yellow to pink) method with a thorough quench in emission attributed to the deprotonation of the secondary amine conjugated to the naphthalimide fluorophore 1-Cu2+ and 2-Cu2+ sense cyanide in ratiometric way via colorimetric and fluorescent changes (C) 2010 Elsevier Ltd All rights reserved